Exams /IGCSE /Beginner / Chemistry — Core

IGCSE Chemistry — Core: What Things Are Made Of and How They Change

IGCSEBeginnerChemistry — Core
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Lesson overview

Particles, bonding, formulas, acids, electrolysis-free practical chemistry and the tests that identify everything.

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Exam guidance · Cambridge IGCSE Command-Word Lens

Pacing

~1 minute per mark; match answer depth strictly to `[1]`, `[2]`, `[3]`, or `[4]` mark allocations.

How IGCSE marks this

Command words govern mark schemes: 'State' = 1 concise fact; 'Describe' = what happens; 'Explain' = why/how using scientific terminology.

Watch out for

Vague everyday wording ('it gets bigger') fails Cambridge mark schemes where exact terms ('rate of collisions increases') are required.

Lesson content

The five ideas Core chemistry reduces to

First, PARTICLES. Solids, liquids and gases differ in how their particles are arranged and move, which explains diffusion (faster for lighter particles and at higher temperature), evaporation and condensation, and the shape of heating and cooling curves — where a plateau is a change of state at constant temperature while the particles' arrangement, not their kinetic energy, changes. A pure substance has fixed melting and boiling points; an impure one melts over a range and lower than the pure value, and that single fact answers most 'how do you know it is pure' questions. Second, ATOMS AND BONDING. Atomic number is the proton count, mass number protons plus neutrons, isotopes are atoms of the same element with different neutron numbers. Electronic configuration in shells (2, 8, 8 for the first twenty elements) explains the group patterns: metals lose electrons and non-metals gain or share them, giving ionic bonding between metal and non-metal (a giant lattice, hard, high melting, conducting only when molten or dissolved) and covalent bonding between non-metals — simple molecules with low melting points and no conductivity, plus the three giant covalent structures whose properties are examinable by name: diamond, graphite and silicon dioxide. Metallic bonding is a lattice of positive ions in a sea of delocalised electrons, which is why metals conduct and deform rather than shatter. Third, FORMULAS AND EQUATIONS. Writing a formula from charges, balancing a symbol equation, and using relative atomic mass to check conservation of mass; the electrolysis-free practical chemistry of Core is largely identification — limewater for carbon dioxide, a glowing splint for oxygen, the pop test for hydrogen, anhydrous copper sulfate for water, cobalt chloride paper for water, and the flame tests and precipitate colours for the common cations and anions. Fourth, ACIDS: the ion that makes a solution acidic (H⁺ in water), the pH scale as logarithmic in effect if not in name, the products of acid with metal, base, carbonate and ammonia, the difference between strong and concentrated (degree of ionisation against amount of solute), and the practical routes to a salt — titration for the soluble salts, excess solid for the insoluble ones, with the six-step crystallisation procedure named. Fifth, the AIR AND THE PERIODIC TABLE: the composition of clean air, rusting as the reaction of iron with oxygen and water (and the sacrificial protection that prevents it), reactivity series used to predict displacement and extraction, and the group trends for alkali metals and halogens stated as far as they go at this tier.

Words the marking scheme expects to see used exactly

DIFFUSION: the net movement of particles from high to low concentration, down a concentration gradient. ISOTOPES: atoms of the same element with the same proton number and different neutron numbers. IONISATION IN WATER: the release of H⁺ ions, which is what makes an acid an acid. STRONG ACID: fully ionised in solution — a statement about molecules, not about amount. DISPLACEMENT: a more reactive element replacing a less reactive one from its compound. ELECTROLYSIS-FREE NOTE: Core asks for the products of the reactions listed, not for electrode half-equations.

Balancing, then counting: the conservation check

Magnesium burns in oxygen: Mg + O₂ → MgO is unbalanced because oxygen appears as pairs on the left. Balance as 2Mg + O₂ → 2MgO; never change a formula to balance an equation, only a coefficient. Now check the mass: 2 × 24 = 48 parts of magnesium with 32 parts of oxygen give 80 parts of magnesium oxide, and 48 + 32 = 80 — conservation of mass holds, which is how you confirm a balanced equation in five seconds. The same three-part reasoning answers the Core question 'why does the mass of a solid increase when it is heated in air': the product contains the oxygen that came from the air, so the mass gain equals the mass of oxygen combined. Write it as 'the magnesium oxide contains the oxygen it reacted with', and the mark is banked.

Acid questions, answered in the marks they award

'Hydrochloric acid is strong but dilute, whereas ethanoic acid is weak but concentrated.' Explain. The answer must separate two axes: strength is the proportion of acid molecules that ionise in water, so HCl ionises fully and ethanoic acid partially (an equilibrium, hence a lower H⁺ concentration for the same molarity); concentration is the amount of acid dissolved per volume, and a concentrated weak acid can still contain more total acid — though usually fewer H⁺ ions — than a dilute strong one. Marks are then given for a testable consequence: the same concentration of each has a different pH (about 1 against about 3), the same rate of fizzing with magnesium is impossible because the H⁺ concentration differs, and both give 1 mole of hydrogen per 2 moles of acid because every molecule can eventually react as the equilibrium shifts. Note the last clause: total gas volume is the same for the same moles of acid, rate is not. That pair of statements answers a large share of Core acid questions.

Lesson summary

Core chemistry is five ideas: particle behaviour, atomic structure and bonding, formulae and equations, the chemistry of acids and salts, and the small set of tests that identify substances. Explain properties by what must be broken — intermolecular forces, ionic bonds, covalent bonds — and never say 'bonds break' when a change of state is described. Strength and concentration are different axes; purity is shown by fixed melting and boiling points; a balanced equation is confirmed by mass conservation.

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